The fluorous version of bis(triphenylphosphine) palladium (II) chloride behaves similarly to it’s non-fluorous counterparts and is compatible with a variety of Pd catalyzed reactions, including Heck, Suzuki, and Sonagashira couplings (1). The catalyst and ligand can then be separated using fluorous solid phase extraction.
1. Schneider, S.; Tzschucke, C.C.; Bannwarth, W. Handbook of Fluorous Chemistry, 2004, 257-272.