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Reagents and catalysts - Phosphine

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Phosphines - single, ethylene spacer

Phosphines - bis, ethylene spacer

Phosphines - tris, ethylene spacer

Phosphines - bis, branched    

Phosphines - tris, no spacer   

Phosphines - tris, branched

Phosphine oxide - single, ethylene spacer

Phosphine oxide - bis, ethylene spacer

Phosphine oxide - tris, ethylene spacer

Phosphine oxide - bis, branched spacer  

PPh3-PdCl2   

 
PPh3-PdCl2
 

 

The fluorous version of bis(triphenylphosphine) palladium (II) chloride behaves similarly to it’s non-fluorous counterparts and is compatible with a variety of Pd catalyzed reactions, including Heck, Suzuki, and Sonagashira couplings (1).  The catalyst and ligand can then be separated using fluorous solid phase extraction.

 

1. Schneider, S.; Tzschucke, C.C.; Bannwarth, W. Handbook of Fluorous Chemistry, 2004, 257-272.

 

Rf NAME/CAS# PROPERTIES CATALOG# QTY PRICE
C8F17 Bis[Diphenyl-[4-(1H,1H,2H,2H-perfluorodecyl)phenyl] phosphine]palladium(II) chloride  
C56H36F34Cl2P2Pd
F034092-0000.1 0.1g Inquire
    FW:  1594.15 F034092-0001 1g Inquire
      F034092-0002 2g Inquire
      F034092-0010 10g Inquire