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Reagents and catalysts - Other

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DIAD  

Dimethyl sulfide

Diacetoxyiodobenzene

Salen-Co complex

Salen (ligand only)

Benzophenone Imine

1,4,7-triazaheptane


 
Salen-Co complex

 

Fluorous salen-Co complex has been reported for the kinetic resolution of terminal epoxides.  The fluorous version allows these reactions to be conducted under fluorous biphasic conditions providing a ready method for recovery and reuse of the catalyst (1,2).  Alternatively, the ligand and metal complex can be removed using F-SPE.  For optically pure versions of F034090, please contact FTI.

 

1. Cavazzini, M.; Quici, S.; Pozzi, G. Tetrahedron, 2002, 58, 3943-3949      

2. Shepperson, I.; Cavazzini, M.; Pozzi, G.; Quici, S. J. Fluorine Chem. 2004, 125, 175-180.

 

Rf NAME/CAS# PROPERTIES CATALOG# QTY PRICE
C8F17 (+/-)trans-1,2-Cyclohexanediamino-N,N'-bis[3-t-butyl-5-(perfluorooctyl)salicylidene]cobalt (II)  
C44H34CoF34N2O2
F034090-0001 1g Inquire
    FW:  1327.6 F034090-0002 2g Inquire