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Reagents and catalysts - Tin

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Tin hydride

Tin azide

Tin bromide

Tin oxide

Allyl tin - ethylene spacer

Phenyl tin - ethylene spacer  


 
Tin hydride

 

Fluorous tin hydride has similar reactivity to tributyl tin hydride, but with the benefit of allowing facile removal of tin byproducts from the desired product either by fluorous solid phase extraction or liquid-liquid extraction.  Fluorous tin hydride can be used in a number of reactions including tin mediated free radical reactions and hydrostannylations (1).

 

1. Curran, D. P.; Hadida, S.; Kim, S. Y.; Luo, Z. Y. J. Am. Chem. Soc. 1999, 121, 6607-6615.

 

Rf NAME/CAS# PROPERTIES CATALOG# QTY PRICE
C4F9 Tris(1H,1H,2H,2H-perfluorohexyl)tin hydride
240497-26-1
C18H13F27Sn
F027048-0002 2g Inquire
    FW:  860.99 F027048-0010 10g Inquire
      F027048-0025 25g Inquire
     
C6F13 Tris(1H,1H,2H,2H-perfluorooctyl)tin hydride
175354-32-2
C24H13F39Sn
F039048-0002 2g Inquire
    FW:  1161 F039048-0010 10g Inquire
      F039048-0025 25g Inquire